Equipment: Nanosurf scanning tunnelling microscopy, model Easyscan STM. Specificationa and sample images are at http://www.nanosurf.ch/.
Readings: None.
Key concepts: Atomic structure of surfaces; tunnelling.
Sample measurement of the surface of graphite..
Below are shown scans of graphite, whose crystal structure is hexagonal.
The images give the appearance of a triangular lattice, but this is only
because half of the surface atoms image as bright spots and the other half
as dim ones.
STM image of surface of graphite (measured in quantum
lab)
In a good top view image of graphite you will see a pattern consisting of white, grey and black spots. To interpret the image correctly: the bright spots mean higher tunneling current and dark spots mean low current.
scan size: 2.0 nm
Out of the lattice model of graphite one can see that
there are two different positions of the carbon atoms in the graphite crystal
lattice (see e.g. R.C. Tatar et al. Phys Rev B 25 (1982) 4126).
One with a neighbouring atom in the plane below (grey)
and one without a neighbour in the lattice below (white). Consequently
the electrical conductivity of the graphite surface varies locally slightly
(different electronic density of states) so that the atoms without neighbours
appear "higher" than the others (see e.g. I.P. Batra et al. Surf Sci 181
(1987) 126). This also causes the lattice constant between the bright ‘hills’
to have the higher value of 0.25nm than the nearest neighbour distance
in the graphite lattice of 0.14nm.